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ChE 6723
Advanced Kinetics
Fall 2009 |
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Meeting |
11:00-12:15 TR, Room SEC E111
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Instructor (Web
link) |
Dr. R. G. Mallinson,
Office Room T322 EC, Ph 325-4378
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Email |
mallinson@ou.edu
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Office Hours
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As available and by appointment
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Text |
Elements of Chemical Reaction
Engineering by H. Scott Fogler, 4th Edition, Prentice
Hall, 2004
(note that if you use an old copy, problems may not match up
and software may not be available)
POLYMATH PROGRAM
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Supplemental
(on Reserve or Reference in the
Engineering Library) |
Chemical Reactor Design for
Process Plants, Vol 1 & 2 by H. F. Rase, J. Wiley and Sons, NY,
1977 (Out of Print)
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Chemical Reactor Analysis and
Design, 2 ed. G. Froment and K. Bischoff J. Wiley and Sons, NY,
1990
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| Handbook of Commercial Catalysts : Heterogeneous
Catalysts; Howard F. Rase; CRC Press, Boca Raton, 2000. |
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Grading |
Two Exams |
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20% + 20% |
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Reactor
Design
Project |
* |
30% (Pt. 1= 5, Pt. 2 = 5, Pt. 3 =
20) |
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Class Participation and Class Notes**
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10% |
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Homework
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20% |
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*
Reactor
Design Project is a complete design solution of a heterogeneous
catalytic reactor problem carried out by individual students.
**Class notes may be turned in at the
end of the semester for review by the instructor |
TOPICS:
Exemplary case studies and examples distributed as
appropriate
Intro, complex kinetics, multiple steps, cracking, polymerization, steady state
assumption, rate determining steps, BIO-KINETICS
Homework 1
HOMEWORK 2
Chpt 7 and
Mallinson
Butane Pyrolysis paper
101
Styrene Polymerization: with polymerization lectures. viscosity and auto
acceleration
102
Cracking ; Different detail of complex kinetics
103
Quench Cooler; heat transfer controlled system
104
Toluene Dealkylation; homogenous free
radical plug flow reactor
(nomenclatue
for Rase case studies)
Fogler Example 7-7
Catalysis, catalytic sequences, kinetics
of adsorption, desorption, surface reactions, rate limiting step, LaNgmuir-
Hinshelwood/Hougen-Watson rate models, practical basis
Chpt 10 and Yang and Hougen paper
(Probable Exam Point)
Mass and heat transport as part of catalytic sequence, interfacial transport,
estimation, physico-chemico picture of porous catalysts, pore diffusion,
generalized modulus, criteria for limitations, non-isothermal, combined external
and internal effects
Chpt 11 and 12 and Kehoe and Butt paper
109
Ammonia Oxidation. mass transfer limited reactor design
107 SO2
Oxidation. complex kinetics. intra-
and inter-particle gradients. algorithm
Deactivation,
Poisoning, coking, kinetics, practical implications, decoking
Chpt 12
(Possible
exam point)
Reactor overview, mass, and energy
balances, multiphase reactors
Fixed bed reactors, pressure drop,
gradient inclusion, hot spots and runaway, 2D models
Chpt 10, some of 8 and Froment paper
105
Shift Converter: equilibrium limit, multiple reactors v. Cost
106
Ammonia Synthesis: equilibrium design. multiple beds, pressure drop v. cost
I11
Steam Reforming: multiple equilibrium
108
Catalytic Reforming : lumping. performance indices. reaction severity
I10
Phthalic Anhydride Production: 2D v. 1D models
